|
Types of Chemical Reactions
|
 |
Doing chemical reactions is the main focus of chemistry
because that's where the action is. That's when something gets made, changed,
or destroyed. So a lot of emphasis is placed on chemical reactions.
Chemical reactions can be understood by these three areas
of focus. A reaction is basically shuffling around the building blocks
of chemistry (atoms/ions/molecules/electrons). Force & energy is what
decides if the reaction occurs and how fast. Mathematics helps you keep
an inventory of all the starting and ending materials.
|
|

|
As mentioned, chemical reactions mostly
focuses on the building blocks. More specifically, how they are put together,
how they dissassemble, and ways to rearrange them.
|
|
Types of Chemical Reactions
Synthesis (Combination)
Decomposition
Single Replacement/Displacement
Double Replacement/Displacement
Oxidation (Combustion)
|
Chemical reactions are often classified
into these six categories. Let's go through them one by one. |
Synthesis (Combination)
Medicines / Drugs
Flavorings
Plastics
Man-made Jewels
|
Synthesis is the making of some compound such as a drug,
a flavoring, a plastic, a jewel.
If atoms were big enough to pick up, we could easily
make all kinds of interesting materials. Of course, they are extremely
small and it's not that easy, but the concept is just as easy.
|
|
|
The synthesis reaction is normally represented by the
letters "A" and "B" forming a compound represented
by "AB". "A" and "B" could represent just
two different elements, or they could be compounds (2 or more elements).
(roll cursor over image for animation)
|
|
|
FLAVORINGS (example of synthesis):
Many articificial flavorings are made from combining an
alcohol with an organic acid. An alcohol has an "OH" group.
An organic acid has a carboxylic acid group (COOH). The questions marks
means there is more attached to these groups. Depending what is attached,
a different flavor is synthesized.
When the alcohol and organic acid combine, water is released.
Below you will see some of the reactions that make the flavors you see
here.
|
|
Below is the synthesis of pear flavoring.
It starts with propyl alcohol (similar to rubbing alcohol) and acetic
acid. As these join, water is released and pear flavoring is synthesized.
Notice that I show three ways of representing the molecules involved.
The top are called "space-filled" models because they show the
space that each atom takes up. You can see that the hydrogen atoms are
smaller than the carbon or oxygen atoms. The middle models are structural
formulas that help show the structure of the molecule. The bottom are
skeletal structural formulas that indicate carbon atoms by a bend in a
line. Carbon atoms are also at the end of line if there's no other element
indicated.
|
|
|
|
Below is the synthesis reaction for apple flavoring. Here
we start with ethanol (2 -carbon alcohol) and butyric acid (it gives rancid
butter that bad odor). When combined they form ethyl butyrate. The name
"ethy" is used when there are a small chain of two carbon atoms
attached. "Butyrate" is the butyric acid without its acidic
hydrogen.
|
|
|
|
Below is the synthesis reaction for pineapple flavoring.
When potatoes are fermented to make alcohol (ethanol), there's also some
amyl alcohol produced (5 carbon alcohol). The smell or taste of amyl alcohol
will make people instantly nauseated. The other reactant is salicylic
acid, which is the active ingredient in many wart removers and anti-dandruff
shampoos. Salicylic acid dissolves skin; however, when these two nasty
chemicals are combined, they make a nice pineapple flavoring that you
eat.
|
|
|
Decomposition Reactions:
Speed up decomposition
* Toxic waste
* Waste
* Fats
* Explosives
Slow down decomposition
*Anti-rusting
*Anti-aging
|
Decomposition Reactions:
We are interested in decomposition reactions for two different
reasons. Sometimes we want to speed up decomposition and other times we
want to slow down decomposition.
|
|
|
Here's an example of decomposition of turkey waste. We
don't eat turkey feathers, heads, feets, and guts, so there's a need to
get rid of this waste. Some companies have figured out ways to break down
all of this waste into an oil. Remember most tissue (muscles, protein,
etc.) in animals are made with very long chains of carbon. The process
is to break down these long chains to about 10 to 20 carbon atoms long.
That makes an oil similar to diesel or biodiesel.
|
 |
The general formula for decomposition is shown here. This
could mean two atoms that are bonded fly apart, or it can mean a larger
molecule with multiple atoms coming apart. (roll
cursor over image to see animation)
Potassium perchlorate is shown. When it decomposes it
releases oxygen. That oxygen is used to speed up the combustion of material
it's in contact with. For example, potassium perchlorate is used in fireworks.
Other material such as paper or sawdust mixed with it will explode because
of this source of oxygen.
|
|
Here's a fun decomposition reaction. The starting compound
is ammonium dichromate. When heated, it begins to decompose into nitrogen
gas, water vapor and powdered chromium (III) oxide. It looks like a volcano
with ash being spread all over the place.
This looks like the compound is burning, but looking at
the chemical equation we see no oxygen is being consumed. So the flame
it produces does not need oxygen. So you can't put out this kind of "fire"
by smothering it like most fires.
|
 |
Here is ammonium dichromate again but this time showing
a molecule of ammonium dichromate decomposing.
(roll cursor over image to see animation).
Whenever you see gases in the products realize that the
reaction can be dangerous because it can build up pressure and cause an
explosion.
|
|
|
Single Replacement:
Another type of reaction is called single replacement
(or single displacement). One element that is not bonded to any other
element (A) comes in to take the place of another element that is bonded
to something (B). Element (B) is now freed.
|
|
|
Sacrificial metal:
An example of a single replacement reaction is when one metal is sacrificed
to save another metal. For example, concrete pillars have iron rebar in
them for strength. However, salt water can quickly react with the iron
to form iron (II) chloride. To prevent this, a metal like zinc or magnesium
is attached to the rebar and will protect the iron. Here's the reaction:
Zn + FeCl2 ->
Fe + ZnCl2
Notice the zinc metal becomes zinc chloride and the iron
that had reacted with the chlorine becomes metallic iron. This preserves
the iron rebar. In a similar manner the aluminum in boats are preserved
by a piece of zinc or magnesium. See the person pointing to a plug of
magnesium that is in embedded in the boat's rudder? That keeps the salt
water from dissolving the aluminum; the magnesium dissolves in aluminum's
place.
|
|
Double Replacement/Displacement:
This kind of reaction is represented by one
compound (represented by "AB") combining with another compound
(represented by "CD"). The reaction happens when "A"
and "C" swap places. Remember these letters represent any element.
For example, let's say you have a pond that is poisoned with dissolved
barium. This can be remedied with a double replacement reaction. That's
because when barium chloride and magnesium sulfate come in contact with
each other, the barium and magnesium atoms swapped places. This reaction
doesn't really occur with solid barium chloride and solid magnesium sulfate.
They need to be dissolved. See description under image.
|
|

|
| The bottom equation above shows
that the ions of barium, chlorine, magnesium, and sulfate are all in water
indicated with the (aq) subscript. In water the ions with the same charge
will stay away from each other, but those with opposite charges attract
each other. So the 2+ magnesium ion will be attracted to the negative 1
chloride ions. They come together but water will pull them apart. Likewise
the 2+ barium ion will be attracted to the negative sulfate ion. This time
the attraction is so strong that water cannot pull them apart. So they form
solid barium sulfate particles that sink to the bottom of the pond. Even
if stirred up, solid barium sulfate is not dangerous to drink because the
barum is bonded so tightly with sulfate that it want come apart to poison
someone. |
|
|
Neutralizing corrosive lye (sodium hydroxide).
Let's say you were using some drain opener (sodium hydroxide)
and accidentally spilled some on the carpet. Lye is very dangerous and
will cause blindness if gotten in the eye and will dissolve skin. The
corrosive part of sodium hydroxide is the hydroxide. Notice that if you
could replace the sodium in NaOH
with hydrogen, you would get HOH,
which is water. A weak acid like vinegar
can supply that hydrogen. Below is the full
reaction. Notice the water in the vinegar will dissolve the sodium hydroxide.
The neutralization takes place when the H+ from the acetic
acid bumps into the OH- from the sodium hydroxide. At that
point they form water (HOH or written as H2O).
|
|

|
|
|
Oxidation reactions:
As the lists states, we are interested in oxidation reactions
for two opposite reasons. Sometimes we want to speed it up and sometimes
slow it down.
|
|
|
Combustion
(a type of oxidation):
Hot air balloons use large propane torches to heat the air in the balloon.
Unfortunately, that much flame can cause a catastrophic fire (see bottom
image). Fortunately, the 11 people in this balloon survived.
All hydrocarbons (like propane) produce carbon dioxide and water as the
combustion products. The unbalanced combustion reaction for propane is:
C3H8 + O2 --> CO2 + H2O
Since propane has 3 carbons, it makes 3 carbon dioxide molecules. Since
it has 8 hydrogen atoms, it will make four H2O molecules. Let's
show that:
C3H8 + O2 --> 3CO2 + 4H2O
Now we need to balance the oxygen on the left side. On the right side there
are 6 oxygen atoms in the 3 carbon dioxide molecules and 4 oxygen atom in
the 4 water molecules. That's a total of 10 oxygen atoms. Since oxygen travels
as O2, we need five O2 molecules to give us 10 oxygen atoms.
So our final balanced equation is:
C3H8 + 5O2 --> 3CO2 + 4H2O |
A
+ B -> AB
AB -> A + B
A + BC -> B + AC
AB + CD -> AC + BD
Hydrocarbon + oxygen -> CO2 + H2O |
Identifying
the type of chemical reaction is easy. It's all about what you can do with
building blocks. |